Crystal structure of the η4-ketimine titanium complex (diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ2 N,C 1}(η5-pentamethylcyclopentadienyl)titanium(IV)
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چکیده
The mol-ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η5-C10H15)(η4-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central TiIV atom, comprising of one penta-methyl-cyclo-penta-dienyl ligand, one bidentate ketimine ligand in an η4-coordination mode and one monodentate di-phenyl-amide ligand. Except for van der Waals forces, there are no significant inter-molecular inter-actions in the crystal.
منابع مشابه
Trichlorido{2-[2-(η5-cyclopentadienyl)-2-methylpropyl]-1-trimethylsilyl-1H-imidazole-κN 3}titanium(IV) tetrahydrofuran hemisolvate
The title compound, [Ti(C(15)H(23)N(2)Si)Cl(3)]·0.5C(4)H(8)O, has been prepared from {2-[2-(η(5)-cyclo-penta-dien-yl)-2-methyl-prop-yl]-1H-imidazolyl-κN(1)}bis-(N,N-diethyl-amido-κN)titanium(IV), (C(12)H(14)N(2))Ti(NEt(2))(2), by reaction with excess of Me(3)SiCl in tetra-hydro-furan (THF) at 353 K. The crystal structure contains THF as adduct solvent, disordered around a center of inversion. T...
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